ESP 32 SuperBEE , Chartes UART with programming adapter

Dear all,
i wondering if TX,RX pins on XBEE socket are shared with USB Programming adapter ?
Unfortunately it seems that TX, and RX pins are from Serial 0 instead of Serial 1, or 2 ?

Question is if i have a chance to use Uart2 or Uart3 of ESP32 ?

Thanks in advance,.